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Size effect, Miniaturization of SnInAg Solder Interconnects

Size effect, Miniaturization of SnInAg Solder Interconnects

Herbert Ipser (ORCID: )
  • Grant DOI 10.55776/P17346
  • Funding program Principal Investigator Projects
  • Status ended
  • Start November 1, 2004
  • End October 31, 2008
  • Funding amount € 271,089
  • Project website

Disciplines

Chemistry (40%); Mechanical Engineering (35%); Physics, Astronomy (25%)

Keywords

    Size Effect, Miniaturization, Lead-Free Solder Interconnect, Sn-Ag-In, Thermomechanical Properties, Thermal Mismatch

Abstract Final report

For the development of novel further miniaturized microelectronic devices with applications below 150C (consumer electronics, telecommunication, commercial aviation, computers) the usually proposed replacement of Pb-Sn by Sn-Ag or Sn-Ag-Cu eutectics as solder materials would be disadvantageous due to the solvus temperature increase of about 40C. The project aims to investigate the applicability of Sn-Ag-In for the miniturization of solder joints avoiding this disadvantage. The methods proposed combine an enhancement of the insight of the underlying processes with testing of thermomechanical stability in practice oriented conditions. Especially the formation and development of metastable and stable intermetallic compounds at boundaries to Cu, Au, Ni., Pd should be investigated and thermal and elastic data should be determined. Miniturization reduces all geometrical dimensions of the solder joint. The reduction of the solder gap due to miniaturization decreases the volume ratio of ductile solder region and brittle intermetallic compound zone at the interface and thus changes the mechanical strength of the solder interconnect. The reduction of the typical diameter of the solder area down into the micrometer range will very likely be the cause for an enhanced crack probability as a mechanical size effect. In this project innovative measuring methods are introduced for sample geometries as present in technical applications. They will be used for the assessment of the reliability of miniturized solder interconnects at realistic mechanical and thermal loading.

For the development of novel further miniaturized microelectronic devices with applications below 150C (consumer electronics, telecommunication, commercial aviation, computers) the usually proposed replacement of Pb-Sn by Sn-Ag or Sn-Ag-Cu eutectics as solder materials would be disadvantageous due to the solvus temperature increase of about 40C. The project aims to investigate the applicability of Sn-Ag-In for the miniturization of solder joints avoiding this disadvantage. The methods proposed combine an enhancement of the insight of the underlying processes with testing of thermomechanical stability in practice oriented conditions. Especially the formation and development of metastable and stable intermetallic compounds at boundaries to Cu, Au, Ni., Pd should be investigated and thermal and elastic data should be determined. Miniturization reduces all geometrical dimensions of the solder joint. The reduction of the solder gap due to miniaturization decreases the volume ratio of ductile solder region and brittle intermetallic compound zone at the interface and thus changes the mechanical strength of the solder interconnect. The reduction of the typical diameter of the solder area down into the micrometer range will very likely be the cause for an enhanced crack probability as a mechanical size effect. In this project innovative measuring methods are introduced for sample geometries as present in technical applications. They will be used for the assessment of the reliability of miniturized solder interconnects at realistic mechanical and thermal loading.

Research institution(s)
  • Universität Wien - 100%
Project participants
  • Brigitte Weiss, Universität Wien , associated research partner
  • Viktor Gröger, Universität Wien , associated research partner
International project participants
  • Jürgen Villain, Universität Augsburg - Germany
  • John Botsis, École polytechnique fédérale de Lausanne - Switzerland

Research Output

  • 202 Citations
  • 8 Publications
Publications
  • 2009
    Title Synthesis of Single-Phase Sn3P4 by an Isopiestic Method
    DOI 10.1021/cm902226s
    Type Journal Article
    Author Ganesan R
    Journal Chemistry of Materials
    Pages 4108-4110
  • 2009
    Title Tin Pest in Sn-0.5Cu Lead-Free Solder Alloys: A Chemical Analysis of Trace Elements
    DOI 10.1007/s11664-009-0958-1
    Type Journal Article
    Author Leodolter-Dworak M
    Journal Journal of Electronic Materials
    Pages 105-108
  • 2009
    Title A novel accelerated test technique for assessment of mechanical reliability of solder interconnects
    DOI 10.1016/j.microrel.2009.06.021
    Type Journal Article
    Author Khatibi G
    Journal Microelectronics Reliability
    Pages 1283-1287
  • 2007
    Title Size effects in small scaled lead-free solder joints
    DOI 10.1007/s10854-007-9349-7
    Type Journal Article
    Author Zimprich P
    Journal Journal of Materials Science: Materials in Electronics
    Pages 383-388
  • 2007
    Title Mechanical Size Effects in Miniaturized Lead-Free Solder Joints
    DOI 10.1007/s11664-007-0278-2
    Type Journal Article
    Author Zimprich P
    Journal Journal of Electronic Materials
    Pages 102-109
    Link Publication
  • 2006
    Title Thermodynamics and phase diagrams of lead-free solder materials
    DOI 10.1007/s10854-006-9009-3
    Type Journal Article
    Author Ipser H
    Journal Journal of Materials Science: Materials in Electronics
    Pages 3-17
  • 2011
    Title Thermochemistry of the nickel–phosphorus system
    DOI 10.1016/j.intermet.2011.02.011
    Type Journal Article
    Author Ganesan R
    Journal Intermetallics
    Pages 927-933
  • 2010
    Title Enthalpies of mixing of liquid In–Sn and In–Sn–Zn alloys
    DOI 10.1016/j.tca.2010.02.008
    Type Journal Article
    Author Rechchach M
    Journal Thermochimica Acta
    Pages 66-72

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