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Rock-Forming Fe2+-Mg Silicate Solid Solutions

Rock-Forming Fe2+-Mg Silicate Solid Solutions

Christian Pruner (ORCID: )
  • Grant DOI 10.55776/P30977
  • Funding program Principal Investigator Projects
  • Status ended
  • Start September 8, 2017
  • End March 7, 2022
  • Funding amount € 366,317
  • Project website

Matching Funds - Salzburg

Disciplines

Chemistry (20%); Geosciences (80%)

Keywords

    Mineralogy, Silicates, Thermodynamics, Silicate Solid Solutions, Spectroscopy, Crystel Chemistry

Abstract Final report

Although the lexicography of the Egyptian language has been under way since nearly two hundred years, this activity has never yielded an inventory of the roots of the language. The roots, abstract elements from which the words or lexemes are derived, differ often from the latter, thus appearing on different places in the alphabetic order of the lexicon: Some stems of Egyptian verbs are derived from their roots by the addition of a prefix, like s-, n-, or m-, and/or by reduplication of the root, as snsn to join, to associate with, as compared with sn, with a similar meaning. The identification of the roots is by no means always an easy task; in many cases it takes both philological and linguistic methods to determine or discern them. Whereas it is important to describe and systematize the mechanics of derivation, further to analyse historical changes of phonetics and writing conventions, the study of the semantics, the development of meaning, is of equal importance. The corpus of the Egyptian language is in constant change. New items may come up whenever a new text is published. With every philological research new meanings and functions or new spellings of existing items may surface. A great collection of lexemes is the Thesaurus Linguae Aegyptiae of the Acadamy of Science in Berlin, which presents online all the items of the big Wörterbuch der ägyptischen Sprache (main volumes accomplished 1931) and all the numerous slips produced for it at that time by an international team of experts of Egyptian texts, but it also keeps track of all later development. There are, however, further lexicographical devices, including the dictionaries of R. Hannig (Old and Middle Kingdoms), of L. Lesko (Late Egyptian), of P. Wilson (Ptolemaic texts), and others. To these should be added the demotic and Coptic dictionaries, for tracing the roots and lexemes into the latest stages of the language. The project Egyptian Root Lexicon shall be executed by the applicant and two younger colleagues. They will be working in the Egyptological Institute of the University of Vienna. The envisaged duration of the project will be 24 months. The resulting lexicon is to be published both as a book and online, in order to facilitate future updating.

Planet Earth, as well as other solid planetary and extraterrestrial bodies, consist to a large degree of crystalline solids, namely minerals. This means that knowledge of the chemical and physical properties of minerals is necessary to obtain an understanding of various processes such as, for example, metamorphism, melting, volcanic eruption and deep earthquake behavior. Such knowledge includes both the microscopic crystal-chemical and the macroscopic physical properties of different rock-forming minerals such as olivine and garnet. Microscopic-scale behavior at the atomistic level determines the macroscopic physical properties of minerals. The role of the former in determining the thermodynamic properties of silicate substitutional solid solutions, for example, is not fully understood. Two key areas need study. The first involves investigating the nature of local structural heterogeneity, which results from the exchange of atoms of different sizes and causes lattice strain. Second, electronic and magnetic behavior arising from transition metals can also affect macroscopic properties. A good scientific understanding of the relationships between crystal-chemical, magnetic and electronic properties and macroscopic physical behavior (e.g., elastic constants, compressibility, thermodynamic functions) is still not at hand. The issues are important for a variety of "applied" scientific questions (e.g., in Geology) and are not just relevant to basic scientific questions regarding the solid state.

Research institution(s)
  • Universität Salzburg - 100%
International project participants
  • Sergio Speziale, Helmholtz Zentrum Potsdam - Germany
  • George R. Rossman, California Institute of Technology - USA

Research Output

  • 114 Citations
  • 18 Publications
Publications
  • 2020
    Title Micro- and nano-size hydrogrossular-like clusters in pyrope crystals from ultra-high-pressure rocks of the Dora-Maira Massif, western Alps
    DOI 10.1007/s00410-020-01693-1
    Type Journal Article
    Author Geiger C
    Journal Contributions to Mineralogy and Petrology
    Pages 57
    Link Publication
  • 2019
    Title An analysis of the magnetic behavior of olivine and garnet substitutional solid solutions
    DOI 10.2138/am-2019-6839ccbyncnd
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
    Pages 1246-1255
    Link Publication
  • 2017
    Title Experimental Mineralogy and Petrology
    DOI 10.1007/978-3-319-39193-9_311-2
    Type Book Chapter
    Author Geiger C
    Publisher Springer Nature
    Pages 1-6
  • 2019
    Title A calorimetric and thermodynamic investigation of cesium uranyl tungstate Cs8[(UO2)4(WO4)4(WO5)2]
    DOI 10.1016/j.jct.2019.05.012
    Type Journal Article
    Author Lelet M
    Journal The Journal of Chemical Thermodynamics
    Pages 48-55
  • 2019
    Title An experimental calorimetric and a DFT?+?U study of the thermodynamic properties of Cs 4 UO 2 4 WO 5 W 2 O 8 O 2 and Cs 4 [ UO 2 7 WO 5 3 O 3 ]
    DOI 10.1016/j.jct.2019.07.015
    Type Journal Article
    Author Lelet M
    Journal The Journal of Chemical Thermodynamics
    Pages 105873
  • 2021
    Title History of the Mineral Sciences: Crystals and their Role in the Development of Atomic Theory
    DOI 10.7185/gold2021.3464
    Type Conference Proceeding Abstract
    Author Geiger C
    Link Publication
  • 2021
    Title A New Paradigm for “Water” in Garnet: Micro- & Nano-Size Hydrogarnet Clusters
    DOI 10.7185/gold2021.3471
    Type Conference Proceeding Abstract
    Author Geiger C
    Link Publication
  • 2022
    Title Nitrogen Incorporation in Potassic and Micro- and Meso-Porous Minerals: Potential Biogeochemical Records and Targets for Mars Sampling
    DOI 10.1089/ast.2021.0158
    Type Journal Article
    Author Nikitczuk M
    Journal Astrobiology
    Pages 1293-1309
    Link Publication
  • 2021
    Title Are the thermodynamic properties of natural and synthetic Mg2SiO4-Fe2SiO4 olivines the same?
    DOI 10.2138/am-2021-7764ccby
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
    Pages 317-321
    Link Publication
  • 2018
    Title Heat capacity and entropy behavior of andradite: a multi-sample and -methodological investigation
    DOI 10.1127/ejm/2018/0030-2741
    Type Journal Article
    Author Geiger C
    Journal European Journal of Mineralogy
    Pages 681-694
    Link Publication
  • 2018
    Title Recent developments and the future of low-T calorimetric investigations in the Earth sciences: Consequences for thermodynamic calculations and databases
    DOI 10.1111/jmg.12291
    Type Journal Article
    Author Geiger C
    Journal Journal of Metamorphic Geology
    Pages 283-295
  • 2018
    Title IR spectroscopy and OH- in silicate garnet: The long quest to document the hydrogarnet substitution
    DOI 10.2138/am-2018-6160ccby
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
    Pages 384-393
    Link Publication
  • 2023
    Title Single-crystal UV/Vis optical absorption spectra of almandine-bearing and spessartine garnet: Part II. An analysis of the spin-forbidden bands of Fe2+, Mn2+, and Fe3+
    DOI 10.2138/am-2022-8500
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
  • 2023
    Title UV/Vis single-crystal spectroscopic investigation of almandine-pyrope and almandinespessartine solid solutions: Part I. Spin-forbidden Fe2+,3+ and Mn2+ electronic-transition energies, crystal chemistry, and bonding behavior
    DOI 10.2138/am-2022-8499
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
  • 2023
    Title Single-crystal UV/Vis absorption spectroscopy of aluminosilicate garnet: Part III. {Fe2+} + [Fe3+] {Fe3+} + [Fe2+] intervalence charge transfer
    DOI 10.2138/am-2022-8756
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
  • 2020
    Title Micro- and nano-size hydrogarnet clusters in calcium silicate garnet: Part II. Mineralogical, petrological, and geochemical aspects
    DOI 10.2138/am-2020-7257
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
    Pages 468-478
  • 2020
    Title Micro- and nano-size hydrogarnet clusters and proton ordering in calcium silicate garnet: Part I. The quest to understand the nature of “water” in garnet continues
    DOI 10.2138/am-2020-7256
    Type Journal Article
    Author Geiger C
    Journal American Mineralogist
    Pages 455-467
  • 2019
    Title Thermodynamic behaviour of grossular–andradite, Ca3(AlxFe3+1-x)2Si3O12, garnets: a calorimetric study
    DOI 10.1127/ejm/2019/0031-2827
    Type Journal Article
    Author Dachs E
    Journal European Journal of Mineralogy
    Pages 443-451

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