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THREE: Elucidating the role of Se(III) radicals in catalysis

Javier Mateos (ORCID: 0000-0002-2358-9183)
  • Grant DOI 10.55776/PAT4712325
  • Funding program Principal Investigator Projects
  • Status ongoing
  • Start February 1, 2026
  • End January 31, 2030
  • Funding amount € 448,383
  • Project website

Disciplines

Chemistry (100%)

Keywords

  • Homogeneous catalysis,
  • Organic Syntheis,
  • Main-group,
  • Selenium,
  • Cross-coupling
Abstract

Chemistry allows us to design and build new molecules that improve our lives from medicines and crop protectants to advanced materials. To create such molecules efficiently, chemists rely on catalysts: substances that make reactions faster and cleaner by lowering the energy required and reducing waste. Among all known elements, selenium stands out because it can easily switch between different chemical states, including rare ones that contain unpaired electrons called radicals. These radicals are highly reactive and can drive chemical transformations in unique ways, yet their behavior in catalytic processes is still poorly understood. Our project, THREE, will uncover how selenium radicals form, how they react, and how they can be reused in catalytic cycles. By combining experiments and computer modeling, we aim to reveal the basic rules that govern their stability and reactivity. Understanding these principles will open new directions for sustainable chemistry, helping scientists design future catalysts that use abundant and less toxic elements instead of precious metals.

Research institution(s)
  • Universität Wien - 100%
Project participants
  • Dennis Kurzbach, Universität Wien , national collaboration partner

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